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…‘fŒ‹‡i‚·‚¢‚»‚¯‚‚²‚¤¤‰p: hydrogen bondj‚ͤ“d‹C‰A«“x‚ª‘å‚«‚ÈŒ´Žqi‰A«Œ´Žqj‚É‹¤—LŒ‹‡‚ÅŒ‹‚т‚¢‚½…‘fŒ´Žq‚ª¤‹ß–T‚Ɉʒu‚µ‚½’‚‘f¤Ž_‘f¤—°‰©¤Ì¯‘f¤ƒÎ“dŽqŒn‚Ȃǂ̌Ǘ§“dŽq‘΂Ƃ‚­‚é”ñ‹¤—LŒ‹‡«‚̈ø—Í“I‘ŠŒÝì—p‚Å‚ ‚顐…‘fŒ‹‡‚ɂͤˆÙ‚Ȃ镪Žq‚ÌŠÔ‚É“­‚­‚à‚Ì(•ªŽqŠÔ—Í)‚Æ’Pˆê‚Ì•ªŽq‚̈قȂ镔ˆÊ‚ÌŠÔ(•ªŽq“à)‚É“­‚­‚à‚Ì‚ª‚ ‚é[2]¡
…‘fŒ‹‡‚Í‚à‚Á‚ς礉A«Œ´Žqã‚Å“d‹C“I‚ÉŽã‚¢—z« (ƒÂ+) ‚ð‘Ñ‚Ñ‚½…‘f‚ª(‰Eã}:…•ªŽq‚Ì—á)ŽüˆÍ‚Ì“d‹C“I‚ɉA«‚ÈŒ´Žq‚Ƃ̊ԂɈø‚«‹N‚±‚·Ã“d“I‚È—Í‚Æ‚µ‚Äà–¾‚³‚ê‚邱‚Æ‚ª‘½‚¢¡‚‚܂褑o‹ÉŽq‘ŠŒÝì—p‚Ì‚¤‚¿¤“Á•Ê‹­‚¢‚à‚̤‚Æ‚µ‚čl‚¦‚邱‚Æ‚à‚Å‚«‚é¡‚½‚¾‚µ…‘fŒ‹‡‚ͲµÝŒ‹‡‚̂悤‚È–³ŽwŒü«‚Ì‘ŠŒÝì—p‚Å‚Í‚È‚­¤…‘f¥”ñ‹¤—L“dŽq‘΂̑Š‘Δz’u‚É‚àˆË‘¶‚·‚é‘ŠŒÝì—p‚Å‚ ‚邽‚ߤ…‘f²µÝ(ÌßÛÄÝ)‚Ì¢·¬¯ÁÎÞ°Ù£‚Æ•\Œ»‚³‚ê‚邱‚Æ‚à‚ ‚é¡
“TŒ^“I‚Ȑ…‘fŒ‹‡(5`30 kJ/mol)‚̧ͤÝÃÞÙÜ°Ù½—Í‚æ‚è10”{’ö“x‹­‚¢‚ª¤‹¤—LŒ‹‡‚ⲵ݌‹‡‚æ‚è‚Í‚é‚©‚ÉŽã‚¢¡…‘fŒ‹‡‚͐…‚È‚Ç‚Ì–³‹@•¨‚É‚¨‚¢‚Ä‚à¤DNA‚È‚Ç‚Ì—L‹@•¨‚É‚¨‚¢‚Ä‚à“­‚­¡…‘fŒ‹‡‚͐…‚̐«Ž¿¤‚½‚Æ‚¦‚ΑŠ•Ï‰»‚È‚Ç‚Ì”M“I«Ž¿¤‚ ‚é‚¢‚͐…‚Æ‘¼‚Ì•¨Ž¿‚Ƃ̐e˜a«‚È‚Ç‚É‚¨‚¢‚ďd—v‚È–ðŠ„‚ð’S‚Á‚Ä‚¢‚é¡
2011”N‚ɤ‘Ûƒ³¥‰ž—p‰»Šw˜A‡(IUPAC)‚É‚æ‚Á‚čì‚ç‚ꂽÀ½¸¸ÞÙ°Ì߂ͤˆÈ‰º‚̂悤‚Ȑ…‘fŒ‹‡‚ÌŒ»‘ã“I‚È’è‹`‚ð’ñˆÄ‚µ‚Ä‚¢‚é¡
The hydrogen bond is an attractive interaction between a hydrogen atom from a molecule or a molecular fragment X?H in which X is more electronegative than H, and an atom or a group of atoms in the same or a different molecule, in which there is evidence of bond formation.
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2019/04/14 12:30
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